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Synthesis, Characterization and Photochromic Studies of Cyclometalated Iridium(Ⅲ) Complexes Containing Spironaphthoxazine Moiety

Jie Liu  Alan Kwun-Wa Chan  Maggie Ng  Eugene Yau-Hin Hong  Nathan Man-Wai Wu  Zuoyi Li  Huilan Zhang  Lixin Wu  Vivian Wing-Wah Yam  
【摘要】:A series of cyclometalated iridium(Ⅲ) complexes has been designed and synthesized, and their photophysical, photochromic and electrochemical properties have been studied. The X-ray crystal structure of complex 2 has been determined. The emission properties of the complexes have been shown to be readily perturbed through the modification of the electronic properties of the phenylpyridine ligand, leading to their tunable optical properties[1] for photochromic and material applications[2].

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