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Copper/Silver-Catalyzed Radical Acylation/Phosphorylation of BODIPY Dyes via Radical-Triggered Oxidative Cross-Coupling

吕帆  焦莉娟  郝二宏  
【摘要】:Boron dipyrromethene(BODIPY) dyes ~1 are now being widelyapplied in diverse research fields.~2 The growing success of thesecompounds is closely associated with their excellent spectroscopicand photophysical properties,and their rich functionalizationchemistry.~3 Traditional functionalization of BODIPY dyes isgenerally achieved by de novo synthesis using suitably prefunctionalized pyrroles.Recently,elegant research progress has beenmade on the postfunctionalization of certain reactive BODIPYdyes,for example,by using halogen or thioether functionalizedBODIPY fluorophores.4 However,these postfunctionalizationmethods often require the use of unstable intermediates and/ora long synthetic route.As we all know that radical reaction has been used as a mild and powerful method to regioselective functionalization of BODIPY dyes.~5 Because of the high reactivity of radical species,radical C-H functionalization on BODIPY can take place under mild conditions without prefunctionalized substrates.Herein,a highly regioselective-acylation/phosphorylation of BODIPY Dyes via radical coupling has been developed.

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