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Visible-Light-Induced Fluoroalkylations

EunJin Cho  
【摘要】:正Recently, visible light photocatalysis has attracted substantial attention due to its environmental compatibility and mechanistic versatility in promoting a large number of synthetically important reactions. We have developed a variety of visible light-mediated radical transformations toaccess fluoroalkyl group-containing molecules, such as –CF_3,~1 –CF_2R,~2–CF_2SPh,~3 and –CF_2OPh~4groups. In the studies, electron deficient carbon-centered fluoroalkyl radicals were successfully generated by the appropriate choice of fluoroalkyl source, photocatalyst, additives, and solvent.

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