Synthesis, Crystal Structure and Second-Order Nonlinear Optical Property of a Novel Pentanary Selenide(K_3I)[InB_(12)(InSe_4)_3]

【摘要】：正Metal chalcogenides with acentric structures are potential NLO materials in the middle and far infrared region.Recently,a novel pentanary selenide(K_3I)[InB_(12)(InSe_4)_3]was obtained via a high-temperature solid-state method using KI as flux.It crystallizes in the noncentrosymmetric hexagonal space group P6_322 with a=13.896(5)and c=9.687(6)?.

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