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Asymmetric Reactions Catalyzed by Chiral N,N'-Dioxide-Metal Complexes

Xiaoming Feng  
【摘要】:正The design of privileged ligands and catalysts allows us to realize a lot of interesting and useful asymmetric reactions.In recent years,we have successfully created a kind of new chiral organocatalyst and ligand,named N.N'-dioxide amides.1,2 They can be synthesized readily from chiral amino acids and amines and act as tetradentate ligands to bind a wide range of metal ions.A great number of asymmetric catalytic

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