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Chiral Catalyst Evolution:Rational Design and Serendipity

【摘要】:正Development of practical methods for asymmetric synthesis of optically active compounds represents a great challenge in the area of chiral chemistry,in which the efficiency of the chiral catalysts is the key issue.As our continuing effort to develop highly efficient chiral catalysts for homogeneous asymmetric reactions,this presentation will focus on the stories of chiral catalyst evolution based on the mechanistic understanding and serendipity.One example is shown in the following scheme.

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