Synthesis and Characterization of one Novel 1D Compound Based on AsW_9-type Polyoxometalates
【摘要】:正A new arsenotungstate,[{Cu(imi)_2}_4{Cu(irni)}_2{AsW_9O_(33)}]·5H_2O(1)(imi=imidazole),has been hydrothermally synthesized and structurally characterized by elemental analysis,IR,TG and single-crystal X-ray diffraction.The compound 1 represents the first example of an unusual trilacunary arsenotungstate substituted simultaneously arsenide fragment and copper complexes.Compound 1
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