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A New Complex with Good Catalytic Properties in Asymmetric Synthesis of Cyclopropanecarboxylic Acids

【摘要】:正 The chemistry of transition metal-sulfur clusters has attracted much attention recently owing to their relevance to certain biological and industrial catalyses, rich structural chemistry, and special reactive properties as well as potential application in nonlinear optical materials. In this article, a new complex, WCu2S4(dppf)2 [dppf = 1,1'-bis(diphenylphosphino)ferrocene] was synthesized through solid state reaction, and it was found that this complex had good catalytic properties in asymmetric synthesis of cyclopropanecarboxylic acids.

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