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Rhodium-Catalyzed Enantioselective Hydrogenation of α-Amino Acrylonitriles

Xiuxiu Li  Cai You  Jiaxin Yang  Shuailong Li  Hui Lv  Xumu Zhang  
【摘要】:正The nitrile group is one of the most versatile functional groups in organic chemistry and can be readily converted to a number of important derivatives in a selective and efficient manner.To date,the preparation of chiralα-amino nitriles mainly relies on carboxyl-modified amino acids,asymmetric cyanation of imines.

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