Unprecedented Hexagonal Bipyramidal Single-Ion Magnets Based on Metallacrowns

Quan-Wen Li Yan-Cong Chen Jun-Liang Liu Ming-Liang Tong

【摘要】：正Single-molecule magnets(SMMs),which exhibit future applications in quantum processing and storage materials,have attracted considerable interests since their discovery in 1990s.It has been recognized that crystal-field(CF)possessing a high rotation symmetry or specific symmetry is apt to enhance the axial anisotropy and minimize the quantum tunnelling of magnetization(QTM),

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