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Precisely Functionalized Molecular Nanoparticles Are Unique Elements for Macromolecular Science:From "Nanoatoms" to Giant Molecules

Stephen Z.D.Cheng  
【摘要】:正We would like to present a unique approach to the design and synthesis of"giant molecules"based on"nano-atoms"for engineering structures across different length and energy scales and controlling their macroscopic properties.The concept of"nano-atoms"refers to shape-persistent molecular nanoparticles(MNPs)with precisely-defined chemical structures and surface functionalities that can serve as elemental parts of building blocks for the precision synthesis of"giant molecules"by methods such as a sequential"click"approach and other efficient organic transformations.Typical"nano-atoms"include those based

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