Microsolvation of monovalent salts in water: Anion photoelectron spectroscopy and ab initio calculations

【摘要】：正In order to understand the microsolvation of monovalent salt in water and provide information about the dependence of solvation processes on different ions, we investigated a series of salt-water clusters, such as LiI(H2O)n- , CsI(H2O)n- , and NaCl(H2O)n- , using photoelectron spectroscopy. The structures of these