A Sensitive Phosphorescent Hypochlorite Chemosensor Based on an Iridium(Ⅲ) Complex with 4'-Methyl-2,2'-bipyridyl-4-carbaldehyde Oxime
【摘要】:正Designed synthesis of a new phosphorescent chemosensor[Ir(ppy)_2(L1)](PF_6)(1)(ppy=2-phenylpyridine,L1 =4'-methyl-2,2'-bipyridyl-4-carbaldehyde oxime) for detection of hypochlorite(ClO~-) is described.Complex 1 is extremely weakly emissive in solution at ambient temperature because the C=N isomerization is the predominant
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