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Synthesis,Crystal Structure and Properties of A 3D Holmium(Ⅲ) Coordination Framework with Pyridine 2,6-dicarboxylate and Oxalate

【摘要】:正A three dimensional holmium(III) coordination polymer formulated as {[Ho_4(pyde)_2(μ_4-C_2O_4)_4·8H_2O]·6H_2O}_n(H_2pydc = 2,6-pyridine-dicarboxylic acid) has been synthesized via the reaction of 2,6-pyridine-dicarboxylic acid and ammonium oxalate with holmium nitrate,and characterized by elemental analysis,IR spectroscopy and X-ray single crystal diffraction.The complex presents 1D zigzag

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