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Synthesis,crystal structure and luminescent properties of a new 2D coordination polymer constructed by Mn(Ⅱ) with pyridine-3,4-dicarboxylate and 2,2’-bipyridine

【摘要】:正A metal-organic framework,[Mn_2(PDC)_2(2,2'-bpy)_2(H_2O)_2]_n·2nH_2O(1)(H_2PDC= pyridine-3,4-dicarboxylic acid,2,2'-bpy=2,2'-bipyribine),has been synthesized under hydrothermal conditions and characterized by elemental analysis and single crystal X-ray diffraction.Compound(1)presents a two-dimensional structure and exhibits intense fluorescent emission upon photo-excitation.

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